Hi,
Do you have a "country" restriction for the payment&shipping methods? Or any kind of restriction? (maybe, minimum order total or something?) Make sure, they are all blank; so that those shipping methods will be displayed. Then, be careful while putting those restrictions.
FYI: If you put a "country" restriction, then the method won't be visible until the customer provides the shipping address (either via "register via checkout" or "Guest checkout")
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Regards,